Harvesters
Patent
1994-09-26
1996-04-02
Killos, Paul J.
Harvesters
C07C 4100
Patent
active
055042589
ABSTRACT:
A process for the efficient production of diisopropyl ether where catalytic distillation is used to increase the yield of product beyond thermodynamic equilibrium limitations has been developed. In a hydration zone the propylene in a feedstock is reacted with water in the presence of a catalyst to effect hydration to produce an effluent stream containing at least water, unreacted propylene, and isopropyl alcohol, and then, in an etherification zone, at least a portion of the effluent stream is further reacted by catalytic distillation in the presence of a catalyst to effect reaction of propylene and isopropyl alcohol to form diisopropyl ether while concurrently separating a propylene rich portion, a diisopropyl ether rich portion and an aqueous portion, and recovering the diisopropyl ether from the diisopropyl ether rich portion.
REFERENCES:
patent: 4935552 (1990-06-01), Child et al.
patent: 5144086 (1992-09-01), Harandi et al.
Barger Paul T.
Funk Gregory A.
Hammershaimb Harold U.
Marker Terry L.
Killos Paul J.
Maas Maryann
McBride Thomas K.
Snyder Eugene I.
UOP
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