Two-stage process for producing diisopropyl ether using catalyti

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C07C 4100

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active

055042589

ABSTRACT:
A process for the efficient production of diisopropyl ether where catalytic distillation is used to increase the yield of product beyond thermodynamic equilibrium limitations has been developed. In a hydration zone the propylene in a feedstock is reacted with water in the presence of a catalyst to effect hydration to produce an effluent stream containing at least water, unreacted propylene, and isopropyl alcohol, and then, in an etherification zone, at least a portion of the effluent stream is further reacted by catalytic distillation in the presence of a catalyst to effect reaction of propylene and isopropyl alcohol to form diisopropyl ether while concurrently separating a propylene rich portion, a diisopropyl ether rich portion and an aqueous portion, and recovering the diisopropyl ether from the diisopropyl ether rich portion.

REFERENCES:
patent: 4935552 (1990-06-01), Child et al.
patent: 5144086 (1992-09-01), Harandi et al.

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