Two-stage process for preparing aromatic polyamide film

Plastic and nonmetallic article shaping or treating: processes – Forming continuous or indefinite length work – Shaping by extrusion

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264184, 2642104, 2642106, 26421118, 26421119, 264212, 264216, 264236, 264347, B29C 7100

Patent

active

049717448

ABSTRACT:
A process for preparing aromatic polyamide film wherein an aromatic diamine and an aromatic diacidchloride are dissolved in an amide polymerization solvent containing an inorganic salt, a partial polymerization is effected at a low temperature to form an optically anisotropic liquid crystalline prepolymer dope, continuously extruding through a film die under a draw ratio or subjecting to a shear and contacting the prepolymer with a second solvent which is a polymerization accelerating-precipitation solvent to obtain an aromatic polyamide film free of crystal defect layer perpendicular to the film axis and having high strength and a high degree of molecular orientation.

REFERENCES:
patent: 4511623 (1985-04-01), Yoon et al.
Journal of Polymer Science; Polymer Physics Edition, vol. 21, 1955-1969 (1983).
Journal of Polymer Science: Polymer Physics Edition, vol. 21, 1957-1983 (1983).

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