Two-stage process for making trimethyl pyridine

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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546250, 546349, C07D21309

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active

047015306

ABSTRACT:
Process for the production of 2,4,6-trimethyl pyridine wherein a carbonyl compound such as acetone is reacted with ammonia in the presence of a condensation catalyst at a temperature in the range from 100.degree. to 200.degree. C. to produce a mixture of products containing 2,2,4,6-tetramethyl-1,2-dihydropyridine which is then purified. The substantially pure dihydropyridine is then contacted with a cracking catalyst at a temperature in the range from 250.degree. to 450.degree. C. to produce 2,4,6-trimethyl pyridine in high yield.

REFERENCES:
patent: 4163854 (1979-08-01), Beschke et al.
patent: 4179576 (1979-12-01), Miyake et al.
patent: 4482717 (1984-11-01), Dinkel et al.

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