Two stage butane haleic anhydride process

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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549260, C07D30760

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active

053609166

ABSTRACT:
Butane is oxidized with molecular oxygen in a dilute state by bringing a mixture of vaporized butane and air of controlled butane content into the presence of a contact vanadium-phosphorus-oxygen catalyst in a first oxidation zone under controlled pressure and temperature conditions, cooling the gaseous effluent from the first oxidation zone to a temperature in the range of 50.degree. to 300.degree. C., introducing a controlled amount of butane into the cooled gaseous effluent from the first oxidation zone, introducing said cooled butane-enriched stream into the second oxidation zone, and bringing the thus butane-enriched mixture into contact with a vanadium-phosphorus-oxygen catalyst disposed in the second zone.

REFERENCES:
patent: 2294130 (1942-08-01), Porter
patent: 4044027 (1977-08-01), Anderson et al.
patent: 4116983 (1978-09-01), Schmidt
Jost, Explosion and Combustion Processes in Gases, McGraw-Hill, N.Y., (1946) pp. 234, 437-440 and 444-454.
Arnold, III et al., Applied Catalysis, vol. 41, pp. 225-239 (1988).

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