Tungsten catalysts

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

Reexamination Certificate

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Details

C502S313000, C502S315000, C502S316000, C208S20800M, C208S21600R, C208S2160PP, C208S243000, C423S244020

Reexamination Certificate

active

07851401

ABSTRACT:
The invention concerns solids comprising a single tungsten oxide layer on a zirconia support and/or titanium dioxide support, characterized in that the tungsten exhibits tetrahedral co-ordination, before and after calcining. The invention also concerns the method for preparing the solids, and their uses as acid catalysis reactions catalyst.

REFERENCES:
patent: 2739132 (1956-03-01), Riedl
patent: 3474042 (1969-10-01), Petrini
patent: 5543036 (1996-08-01), Martenak et al.
patent: 1 249 079 (1971-10-01), None
patent: WO 01 48119 (2001-07-01), None
J.C. Yori et al. “n-butane isomerization on tungsten oxide supported on zirconia”. Applied Catalysis A: General 163 (1997) 165-175.
Vaudagna et al. “Influence of the tungsten oxide precursor on WOx-ZrO2 and Pt/WOx-ZrO2 properties” Applied Catalysis A: General 164 pp. 265-280 (1997).
Barton et al. “Structure and Electronic Properties of Solid Acids Based on Tungsten Oxide Nanostructures”. J. Phys. Chem. B 1999, 103, 630-640.
Salvati et al. “Surface spectroscopic study of tungsten-alumina catalysts using x-ray photoelectron, ion scattering, and raman spectroscopies”. J. Phys. Chem. 1981, 85, 3700-3707.
Parera, J.M. et al., “n-butane isomerization on tungsten oxide supported on zirconia”,Applied Catalysis A: General, Elsevier Science, Amsterdam, NL, vol. 163, No. 102, Dec. 5, 1997, pp. 165-175.
Sohn, Jong Rack et al., “Characterization of zirconia-supported tungsten oxide catalyst”,Langmuir, vol. 14, No. 21, 1998, pp. 6140-6145, XP002234339.
Vuurman, M.A. and Wachs, I.E., “Structural determination of supported V205-WO3/Ti02 catalysts by in situ Raman spectrometry and X-ray photoelectron spectroscopy”,Journal of Physical Chemistry, vol. 95, No. 24, 1991, pp. 9928-9938, XP002234340.

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