(+),(-)-Tropicamide O-.beta.-B-glucuronic acid, its diastereomer

Details (+),(-)-Tropicamide O-.beta.-B-glucuronic acid, its diastereomer (+),(-)-Tropicamide O-.beta.-B-glucuronic acid, its diastereomer

1982-05-24

1984-04-17

Jiles, Henry R.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

536 173, 424 60, C07H 1526

Patent

active

044436084

ABSTRACT:
An in vitro enzymatic process which efficiently converts (+,-)-tropicamide to essentially pure (+), (-)-tropicamide O-.beta.-D-glucuronide. This product is then separated, advantageously, into the novel compounds (+)-tropicamide O-.beta.-D-glucuronide and (-)-tropicamide O-.beta.-D-glucuronide. The products disclosed herein absorb ultraviolet light, and, thus, can be incorporated into suitable plastic films which are then useful for screening out harmful ultraviolet radiation for the protection of packaged goods. Also the products can be used to protect the skin against burning by sunlight.

REFERENCES:
patent: 3240777 (1966-03-01), Sarett et al.
patent: 4153697 (1979-05-01), Hornke et al.
patent: 4292250 (1981-09-01), DeLuca et al.
Smith, P.A.S., "The Chemistry of Open-Chain Organic Nitrogen Compounds" (1965) pp. 142-143.
Ando, et al., Synthesis of Mycophenolic Acid .beta.-D-Glucuronide and Its Antitumor Activity, J. Antibiotics, 23, 408-413 (1970).
Johnson, et al., Glucuronidation of Lipophilic Substrates, Prep. Biochem. 9, 391-406 (1979).

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