Trisstannoxanes useful for polymerizing macrocyclic poly(alkylen

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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549210, 549212, C07F 722

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active

053860373

ABSTRACT:
Novel trisstannoxanes are prepared by the reaction of a dialkyltin oxide with a trihydroxy compound such as 1,1,1-tris(hydroxymethyl)propane. They may be employed as catalysts for the preparation of branched polyesters from macrocyclic polyester oligomers. They are less susceptible than previously known catalysts to the presence of acidic impurities in the oligomer compositions.

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patent: 5231161 (1993-07-01), Brunelle et al.
patent: 5321117 (1994-06-01), Brunelle et al.
Liu et al., Polymer Preprints, Am. Chem. Soc., 33(1), 1111-1112 (1993).

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