Triple ions of 1,2- and 1,4-dicarbonyl compounds and analogs the

Details Triple ions of 1,2- and 1,4-dicarbonyl compounds and analogs the Triple ions of 1,2- and 1,4-dicarbonyl compounds and analogs the

1978-09-25

1980-05-06

Higel, Floyd D.

Chemistry: electrical and wave energy

Processes and products

Processes of treating materials by wave energy

204158HE, 260192, 2603478, 260369, 260396R, 260396N, 260464, 2604655, 260621P, 544336, 260 65R, 26034611, 528225, 2604655R, 568716, B01J 110, B01J 112, C07G 1300, C07C10702

Patent

active

042016380

ABSTRACT:
Stable paramagnetic alkali radical cationic triple ions of selected 1,2 and 1,4 dicarbonyl compounds and their nitrogen-containing analogs have been produced by both conventional alkali metal reduction of an appropriate organic compound and by a novel process in which the selected 1,2 or 1,4 dicarbonyl compound or the nitrogen containing analog thereof is mixed with an alkali tetraphenylborate and irradiated under ultraviolet light.

REFERENCES:
patent: 2661354 (1953-12-01), Schmidle
patent: 3595922 (1971-07-01), Manos
Mauser et al., Zeit. Fur Naturforschung, vol. 276, pp. 1354-1359, (1972).
Vlasova et al., Chemical Abstracts, vol. 70, Item #15301t, (1969).
Brandon et al., J. Chem. Soc., (London), vol. of 1961, pp. 4273-4280.
Harada et al., Bull. Chem. Soc., Japan, vol. 34, pp. 585-586, (1961).

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