Refrigeration – Refrigeration producer – Sorbent type
Reexamination Certificate
1999-12-23
2001-12-04
Bennett, Henry (Department: 3744)
Refrigeration
Refrigeration producer
Sorbent type
C062S489000
Reexamination Certificate
active
06324865
ABSTRACT:
FIELD OF THE INVENTION
The present invention relates to a triple-effect absorption chiller with vapor compression units, more specifically, a triple-effect absorption chiller of a single serial-flow cycle, where one or more vapor compressors are connected to medium-, high-temperature generator, or evaporator, thereby compressing refrigerant vapor therefrom and maintaining the high-temperature generator at below 170°C.
BACKGROUND OF THE INVENTION
In general, absorption chillers use LPG, LNC, waste heat, or solar heat as an energy source, and accomplish the cooling effect by operating the absorber, condenser, evaporator and generator to circulate a working fluid of refrigerant/absorbent pair. Contrary to the conventional compression chillers using an energy source of electricity, the absorption chiller which employs heat as an energy source has been regarded as one of the alternative means for overcoming pending problems of the electrical overload during summer season and the regulation of banning the CFC use.
On the other hand, a triple-effect absorption chiller combining medium- and high-temperature generators with the conventional absorption chillers has been developed to maximize the energy consumption efficiency by way of employing refrigerant vapor from high-temperature generator(‘GH’) as a heat source for medium-temperature generator(‘GM’), and the refrigerant vapor from GM as a heat source for low-temperature generator(‘GL’), respectively. The triple-effect absorption chiller is improved in terms of the energy efficiency by about 30%, compared to the conventional double-effect absorption chiller with only one GH.
The triple-effect absorption chiller is, however, proven to be less satisfactory in a sense that inorganic salt-based(e.g. lithium bromide) working fluid to maintain the temperature of GH at 200° C. or more, may bring about a serious corrosion in the chiller and non-condensible vapor formation at a temperature range of over 170° C., eventually decreasing the efficiency of chiller.
In this regard, several kinds of absorption chillers have been suggested in the art, to improve the efficiency of conventional absorption chillers and the corrosion problems of triple-effect absorption chillers.
For example, U.S. Pat. Nos. 4,520,634 and 5,205,136 and Grossman et al.(see: Grossman, G. et al.,
ASHRAE Trans.,
100(1): 452-462, 1994) describe multiple-effect absorption chillers whose efficiency is highly improved, while remaining the corrosion problems caused by working fluid operating at a high temperature.
Further, U.S. Pat. No. 4,732,008 teaches a triple-effect effect absorption chiller employing two refrigerating circuits to overcome the said corrosion problems, and Ouimette et al employs one additional high-temperature circuit of less corrosible working fluid to the conventional double-effect absorption chiller(see: Ouimette, M. S. and Herold, K. E.,
Proc. International Absorption Heat Pump Conference AES
vol. 31, American Society of Mechanical Engineers, pp233-241, 1993).
U.S. Pat. No. 4,171,619 and Sawada et al.(see: Sawada, N. et al.,
Proc. International Absorption Heat Pump Conference AES
vol. 31, American Society of Mechanical Engineers, pp471-476, 1993) illustrate a variety of methods for applying compressors to improve the efficiency of single-effect absorption chiller. In addition, Boer et al disclose a double-effect absorption chiller with one compressor employing a working fluid of methanol-glycerol to improve the efficiency of the chiller(see: Boer, D. et al.,
Proc. International Absorption Heat Pump Conference AES
vol. 31, American Society of Mechanical Engineers, pp483-486, 1993).
SUMMARY OF THE INVENTION
The present inventors have made an effort to solve the corrosion problems of the triple-effect absorption chiller with a single serial-flow cycle, by employing the most effective working fluid of inorganic salt(absorbent)-water(refrigerant), and found that a triple-effect absorption chiller with one or more vapor compressors connected to medium-, high-temperature generator or evaporator to compress the refrigerant vapor coming from the said generators or evaporator, successfully lowers the temperature of GH to a preferable range of below 170° C., and prevents the corrosion of metal parts of the chiller.
A primary object of the present invention is, therefore, to provide an improved triple-effect absorption chiller with vapor compression units.
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Boer et al., Combined Vapor Compression-Double Effect Absorption Cycle for Air Conditioning: A New High Performance Cycle, International Absorption Heat Pump Conference, AES31:483-486 (1993).*
E.A. Groll and R. Radermacher, Vapor Compression Heat Pumpt with Solution Circuit and Desorber/Absorber Heat Exchange,International Absorption Heat Pump Conference, AES31:463-469 (1993).
Norio Sawada et al., Cycle Simulation and Cop Evaluation of Absorption-Compression Hybrid Heat Pumps: Heat Amplifier Type,International Absorption Heat Pump Conference, AES31:471-476 (1993).
Akihiro Kawada et al., NH3/H2O System Absorption-Compression Hybrid Heat Pump Cop Evaluation of Temperature Amplifier Type Heat Pumps,International Absorption Heat Pump Conference, AES31:477-481 (1993).
D. Boer et al., Combined Vapor Compression-Double Effect Absorption Cycle for Air Conditioning: A New High Performance Cycle,International Absorption Heat Pump Conference, AES31:483-486 (1993).
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R.C. DeVault and G. Grossman, Triple-Effect Absorption Chiller Cycles,International Gas Research Conference, 1500-1508 (1902).
Kim Jin Soo
Lee Huen
Bennett Henry
Darby & Darby
Jiang Chen-Wen
Korea Advanced Institute of Science and Technology
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