Tripinyltrioxanes

Details Tripinyltrioxanes Tripinyltrioxanes

1975-10-31

1979-09-18

Milestone, Norma S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

C07D32304

Patent

active

041682700

ABSTRACT:
Tripinyltrioxanes of the general formula (I): ##STR1## in which the radicals Pin are either dextrorotatory (+) or laevorotatory (-) pinyl radicals; a process for the production of (I) by treatment of an enantiomeric mixture of (+)-3-formylpinane and (-)-3-formylpinane (II) with an acid in an organic solvent and fractional precipitation of the trimeric compound (I); and redissociation of (I) into the pure enantiomers (II) with a catalytic amount of an acid.

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