Triphenylphosphine oxide complex process

Organic compounds -- part of the class 532-570 series – Organic compounds – Phosphorus containing

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544260, C07F 953, C07D47508

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active

06011181&

ABSTRACT:
A process for reducing the level of tri-substituted phosphine, arsine and/or stibine oxide from a mixture comprising a desired product and at least one such oxide is provided, comprising the addition of a metal salt to the mixture to form a complex with the oxide, and removing the complex from the mixture. This process has particular utility for removing triphenylphosphine oxide from a mixture--a task that was previously hard to perform.

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patent: 5292973 (1994-03-01), Fukumoto et al.
Lincoln et al., Aust. J. Chem., 1981, vol. 34, pp. 283-289.
Camp et al., Aust. J. Chem., 1988, vol. 41, pp. 1835-1839.
Itzstein et al., Synthetic Comm., 1990, vol. 20, No. 13, pp. 2049-2057.
Kang et al., Tet. Lett., vol. 37, No. 52, 1996, pp. 9317-9320.

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