Trioxane derivatives, and method for the chemiluminescence

Details Trioxane derivatives, and method for the chemiluminescence Trioxane derivatives, and method for the chemiluminescence

1992-12-04

1994-09-20

Housel, James C.

Chemistry: analytical and immunological testing

Optical result

With fluorescence or luminescence

549367, 436100, G01N 2176, C07D32304

Patent

active

053488903

ABSTRACT:
Trioxane derivatives represented by the formula (I): ##STR1## wherein A and RA are the same with or different from each other, and represent a substituted or unsubstituted aliphatic hydrocarbon group, respectively, or represent R.sub.1 --X.sub.1 --or R.sub.2 --X.sub.2 --in which X.sub.1 and X.sub.2 represent independently a divalent organic residue, and R.sub.1 and R.sub.2 represent independently carboxyl group, amino group, hydroxyl group or mercapto group, and Z represents hydrogen atom, halogen atom, methyl group, ethyl group or propyl group, or carboxyl, amino, hydroxyl or mercapto group through a divalent organic residue, and process for the preparation thereof, as well as method for chemiluminescence comprising mixing the trioxane derivatives and a base.

REFERENCES:
Yamamoto et al. "Synthesis and Reactions of 5-Arylamino 1,2,4 trioxans" JCS Perkin I, 1980. pp. 2300-2303.
Nakamura et al. "Synthesis and Chemiluminescence of [5(2 Pyridyl), (2-pyrazimyl)-,and Substituted 2 Pyrazinyl)amino] 1,2,4 trioxanes" Bull Chem. Soc. Jpn. vol. 61, No. 10 pp. 3776-3778 (1988).
Teranishi et al., "No Electron Donating Substituent Effect on The Singlet Excited State Formation from the 5 (5 Aryl 2-Pyrazinylamino) 1,2,4 trioxanes" Bull Chem. Soc. Jpn vol. 62 pp. 2009-2012 (1989).
Jefford et al., "New Chemistry of Zwitterionic Peroxides arising by Photooxidation of enol ethers" Tetrahedron vol. 41 No. 11 pp. 2081-2088 (1985).

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