Trimerization of aromatic isocyanates catalyzed by certain ammon

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 25AW, 260 775AC, 260 775NC, 260248NS, 2605676M, 428425, C08G 1800

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039805948

ABSTRACT:
Quaternary ammonium salts or inorganic and organic oxygen acids having pK values (where pK is the negative log of the dissociation constant) for at least one of the dissociable hydrogen atoms equal to or greater than 2.0 in aqueous solution are employed as extremely efficient catalysts for trimerization of organic isocyanates, particularly aromatic isocyanates, to isocyanurates and for urethane formation.

REFERENCES:
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patent: 3487080 (1969-12-01), Matsui et al.
patent: 3657161 (1972-04-01), Bernard et al.
patent: 3711444 (1973-01-01), Allen et al.
patent: 3715337 (1973-02-01), Allen et al.
patent: 3817939 (1974-06-01), Allen et al.

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