Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1975-10-01
1976-11-16
Sebastian, Leland A.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260429R, 2604292, 2604297, 260448A, C07F 500, C07F 506
Patent
active
039924246
ABSTRACT:
Trifluoromethyl-substituted compounds, are formed in a corona discharge or glow discharge plasma of trifluoromethyl radicals from an organic trifluoromethyl source. A substrate possessing easily replaceable ligands such as halogen or carbonyl, is initially contacted either in the plasma and within a short distance from a downstream visible edge of the plasma or outside of the visible portion of the plasma and within a short distance from the downstream visible edge, to effect a substitution of the halogen or carbonyl ligand on the substrate with a trifluoromethyl radical without substantial decomposition of the substrate.
REFERENCES:
patent: 3794671 (1974-02-01), Wilkinson
Jacob et al., Chem. Soc. Journal, Chemical Communications, 1973, No. 4, pp. 104-105.
Lagow et al., J. Am. Chem. Soc., vol. 97, pp. 518-522 (1975).
Gerchman Lois L.
Jacob Robert A.
Lagow Richard J.
Cook Paul J.
Massachusetts Institute of Technology
Sebastian Leland A.
Shaw Robert
Smith, Jr. Arthur A.
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