Tricyclo[6.2.1.0.sup.2,6 ]undeca-2(6)-ene and process for hydrid

Details Tricyclo[6.2.1.0.sup.2,6 ]undeca-2(6)-ene and process for hydrid Tricyclo[6.2.1.0.sup.2,6 ]undeca-2(6)-ene and process for hydrid

1976-10-20

1978-04-25

O'Keefe, Veronica

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260666M, C07C 1328

Patent

active

040862852

ABSTRACT:
Tricyclo[6.2.1.0.sup.2,6 ]undeca-2(6)-ene is disclosed and there is further disclosed a process for the hydride transfer reduction rearrangement of tricyclo[6.2.1.0.sup.2,6 ]undeca-2(6)-ene having the formula (I): ##STR1## by subjecting tricyclo[6.2.1.0.sup.2,6 ]undeca-2(6)-ene having the formula (I) to rearrangement with concentrated sulfuric acid in the presence of a hydride source to convert it to 4-homoisotwistane (tricyclo[5.3.1.0.sup.3,8 ]undecane) having the formula (II): ##STR2##

REFERENCES:
naotake Takaishi et al., Chemical Abstracts, vol. 84: 10478j, 1976, [J. Org. Chem., 1976, 41 (5), 771-775].
Naotake Takaishi et al., J. Org. Chem., vol. 40, No. 3, 276-281, 1975.
Naotake Takaishi et al., J. Org. Chem., vol. 40, No. 10, 1483-1487, 1975.

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