Trichlorosilane production process

Chemistry of inorganic compounds – Silicon or compound thereof – Halogen containing

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423350, C01B 3302

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active

045267693

ABSTRACT:
A process for producing trichlorosilane and equipment for practicing that process are disclosed. The process is a two stage process which combines the reaction of silicon tetrachloride and hydrogen with silicon with the reaction of hydrogen chloride with silicon. In one embodiment of the invention a two stage reactor is provided with a first stage heated to a temperature of about 500.degree.-700.degree. C. and a second stage maintained at a temperature of about 300.degree.-350.degree. C. Each of the first and second stages of the reactor are charged with silicon particles. A mixture comprising hydrogen and silicon tetrachloride are flowed through the silicon particles in the heated first stage to cause a partial hydrogenation of the silicon tetrachloride. The effluent from the first stage includes trichlorosilane and unreacted hydrogen and silicon tetrachloride. Hydrogen chloride is added to this effluent and the mixture of gases are passed through the silicon particles in the second stage of the reactor.

REFERENCES:
patent: 3148035 (1964-09-01), Enk
patent: 3681036 (1972-08-01), Schwarz et al.
patent: 4117094 (1978-09-01), Blocher, Jr. et al.
Mui, J. Y. P., "Investigation of the Hydrochlorination of SiCl.sub.4 ", Final Report, Jet Propulsion Lab, Cal. Inst. Tech., Contract No. 956061, Apr. 1983.

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