Trichloroethanimidic acid esters

Organic compounds -- part of the class 532-570 series – Organic compounds – Imidate esters

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548240, 548478, 548546, 548547, 549347, 549496, 564209, 564224, 546153, 556420, C07C11918, C07C103127, C07D26102, C07D32100

Patent

active

046925384

ABSTRACT:
New and more efficient chemical processes are provided for preparing (.alpha.S, 5S)-.alpha.-amino-3-chloro-2-isoxazoline-5-acetic acid (AT-125), (.alpha.S, 5S)-.alpha.-amino-3-bromo-2-isoxazoline-5-acetic acid (bromo AT-125) and the C-5 epimers thereof. The disclosed processes allow the above-mentioned antitumor agents to be produced in high yield and purity with substantially fewer steps than prior art chemical procedures.

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Beilstein, Handbook of Organic Chemistry, 1(2), 567.
Fiebigs, Ann. Chem., 1980, 703-714.

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