Triblock polymers of a monovinyl aromatic compound and myrcene

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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C08F29704

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active

043749577

ABSTRACT:
A tacky thermoplastic elastomeric linear triblock polymer corresponding to the formula A-B-A is made from a monovinyl aromatic hydrocarbon and myrcene. A is a polymer block of a monovinyl aromatic hydrocarbon, e.g. styrene, having an average molecular weight between 2,000 and 100,000 and a glass transition temperature above 25.degree. C. B is a polymeric block of myrcene (7-methyl-3-methylene-1,6-octadiene, C.sub.10 H.sub.16) having an average molecular weight between 10,000 and 1,000,000 and a glass transition temperature below -40.degree. C. B constitutes from 40 to 80 percent of the total. The products are made by sequential polymerization with an organolithium initiator.

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Marvel, C. S. et al., "Polymyrcene", Journal of Polymer Science, vol. XLV, pp. 25-34, (1960).
Sivola, Arto, "The n-Butyllithium-Initiated Polymerization of Myrcene and its Copolymerization with Styrene", Acta Polytechnica Scand., Chem. Incl. Metall Ser. No. 134, 65 pp., (1977), (in English).
Quirk, R. P. et al., "Anionic Polymerization of Myrcene New Block Copolymers", Program Preprint 36th ACS Fall Scientific Meeting Midland, Mich., p. 24, Nov. 1, 1980.

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