Triazene oxide-transition metal complexes as hydrosilylation cat

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

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556 12, 556136, 556137, 556479, 528 14, 528 15, 546 4, 546 12, 546 14, 549 3, 549206, 549212, 549214, 548402, 534551, 534552, 502152, 502158, 502167, C07F 708, C07F 710, C07F 1500

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054969611

ABSTRACT:
Organosilicon compounds having Si-bonded hydrogen atoms are reacted with organic compounds having aliphatic multiple bonds in the presence of triazene oxide-transition metal complexes. The triazene oxide-transition metal complexes are activated by heating at temperatures of from 50.degree. C. to 250.degree. C. and/or by irradiation with light.

REFERENCES:
patent: 3814730 (1974-06-01), Karstedt
patent: 5426200 (1995-06-01), Dauth et al.
R. L. Dutta, R. Sharma; J. Sci. Ind. Res., 40(11) (1981) 715-737.
D. N. Purohit et al.; Rev. Anal. Chem., 11(3-4), 269 (1992).

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