Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1976-09-03
1978-03-07
Higel, Floyd D.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260146R, 260147, 260148, 260150, 260151, C09B 4508, C09B 4518, C09B 4528, D06P 110
Patent
active
040779530
ABSTRACT:
A tri- or tetra-dentate metal complex having the formula ##STR1## wherein A is an aryl or heterocyclic residue, B is an aliphatic, aryl or heterocyclic residue, R is an alkyl, cycloalkyl, aryl, aralkyl or heterocyclic residue or R is the atoms required to complete, together with A and Y, a heterocyclic residue, Y is O, S or N--R" wherein R" is the atoms required to complete, together with A and Y, a heterocyclic residue, X is O, S, CO.sub.2 or N--R wherein R has its previous significance, and when X is CO.sub.2, R' is a methylene residue and when X is O, S or N--R, R' is a carbon chain, which may form part of an aromatic or heterocyclic ring, and having 2 or 3 carbon atoms between the nitrogen atom and the X substituent, M is a Zn, Cu or Ni atom, n and m are the same or different and each is 0 or 1 and P is 1 or 2, and when p is 1, C is a hydrogen atom attached to one of the residues A, B, R or R' and when p is 2, C is either a direct bond linking two residues, A, B, R or R' or is an alkylene, arylene or aralkylene residue linking two residues A, B, R or R', which is useful for coloring organic material preferably a lacquer, paint or printing ink.
REFERENCES:
patent: 2822360 (1958-02-01), Ackermann
patent: 2824094 (1958-02-01), Ackermann et al.
patent: 3125561 (1964-03-01), Beffa et al.
Venkataraman, "The Chemistry of Synthetic Dyes", vol. III, pp. 353-357 (1970).
McCrae James McGeachie
Midcalf Christopher
Cavalieri Vincent J.
Ciba-Geigy Corporation
Higel Floyd D.
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