Tri-branched biologically active copolymer

Drug – bio-affecting and body treating compositions – Solid synthetic organic polymer as designated organic active... – Ion exchange resin

Reexamination Certificate

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Reexamination Certificate

active

07811555

ABSTRACT:
The present invention discloses a tri-branched copolymer comprising a hydrophobic domain, a hydrophilic domain, a biologically active moiety, and an alkyl core of 2 to 10 carbon atoms. The hydrophobic domain, the hydrophilic domain, and the biologically active moiety are separately linked to the alkyl core of 2 to 10 carbon atoms through three functional groups, wherein said three functional groups are independently the same or different. Preferably, the tri-branched copolymer is prepared through reversible addition fragmentation transfer (RAFT) polymerization and conjugation reactions. The present invention also discloses a coating composition for applying on at least a portion of one surface of an article. The coating composition comprises the inventive tri-branched copolymer. In another aspect, the present invention discloses an article having the inventive coating composition thereon. Preferably, the article is a medical device or a component of a medical device.

REFERENCES:
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patent: 6238799 (2001-05-01), Opolski
patent: 6566506 (2003-05-01), Greenwald et al.
patent: 2003/0113477 (2003-06-01), Timmons et al.
patent: 2005/0266038 (2005-12-01), Glauser et al.
patent: WO 03/059973 (2003-07-01), None
patent: WO 03/078489 (2003-09-01), None
European Search Report dated Jun. 24, 2008 for EP Application No. EP 06256638.
Feng, Xiao-Shuang et al: “Synthesis of Amphiphilic Miktoarm ABC Star Copolymers by RAFT Mechanism Using Maleic Anhydride as Linking Agent” Macromolecules, vol. 35, No. 13, 2002, 4888-4893.
Shi, Peng-Jie et al., “Block and star block copolymers by mechanism transformation X . . . ”European Polymer Journal, 2004, 20, 1283-1290.
www.surmodics.com.

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