Treatment of offgas from aluminum chloride production

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture

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423240, 423241, 423242, 423245, 423246, 423336, 423608, 423624, 423636, 423210, C01B 700

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active

042094968

ABSTRACT:
A process for treatment of aluminum chloride production offgas containing Cl.sub.2, CO, CO.sub.2, HCl, COCl.sub.2, COS, SO.sub.2, N.sub.2, SiCl.sub.4 and metal chlorides by reaction with water vapor in the presence of an alumina or low iron sand catalyst to convert SiCl.sub.4 and metal chlorides to the corresponding oxides and HCl; subsequent reaction of COCl.sub.2 with water vapor in the presence of an activated carbon catalyst to form CO.sub.2 and HCl; and removal of HCl by contacting the offgas with liquid water. Reaction with steam in the presence of alumina catalyst prior to reaction with steam in the presence of an activated carbon catalyst prolongs the useful life of the activated carbon catalyst and avoids the necessity of removing SiCl.sub.4 and metal chlorides from the offgas by adsorption onto dry activated carbon prior to contacting the activated carbon catalyst with offgas.

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