Electrolysis: processes – compositions used therein – and methods – Electrolytic material treatment – Water – sewage – or other waste water
Reexamination Certificate
1999-05-12
2001-03-06
Gorgos, Kathryn (Department: 1741)
Electrolysis: processes, compositions used therein, and methods
Electrolytic material treatment
Water, sewage, or other waste water
C205S766000, C204S515000
Reexamination Certificate
active
06197187
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a method for treating contaminated media, including soils and groundwaters. In particular, the invention relates to treating soil that is contaminated with halogenated hydrocarbons, such as halogenated hydrocarbons in aqueous compositions.
2. Description of the Related Art
Halogenated hydrocarbons, such as chlorinated hydrocarbons, are also known as chlorinated solvents (hereinafter collectively referred to as “chlorinated solvents”). Halogenated hydrocarbons have low flammability and are fairly stable, both chemically and biologically. They are commonly used in industry as chemical carriers and solvents, paint removers, and cleaners. The cleaning applications typically include metal degreasing, circuit board cleaning, metal parts cleaning, and dry cleaning. Chlorinated solvents are also used as intermediates in chemical manufacturing and as carrier solvents for pesticides and herbicides.
Chlorinated solvents are stable compounds, are relatively toxic at low levels, and many chlorinated solvents have been classified as suspected or confirmed carcinogens. Chlorinated solvents are prevalent contaminants in groundwater and soil because of their widespread use and long-term stability. Groundwaters and soils have become contaminated by chlorinated solvents from various sources. These sources include, but are not limited to, disposal facilities, chemical spills, and leaking underground storage tanks. Chlorinated solvents also may be released to the environment through the use, loss, or disposal of a neat liquid, and alternatively through the use or disposal of wash and rinse waters containing residual solvents.
Movement and dispersion of chlorinated solvents in the subsurface soils and groundwaters vary depending on whether the solvents are released as a neat liquid or in a dissolved form. If released in a dissolved form, chlorinated solvent migration is governed largely by hydro-geological conditions and processes. The presence of solubilizing agents, such as soaps from wash waters, counteracts natural soil sorption-retardation mechanisms for chlorinated solvents, and enhances migration of the chlorinated solvents.
If chlorinated solvent is released as a neat liquid, the chlorinated solvent migrates through soil under the force of gravity. A portion of the chlorinated solvent is typically retained in soil pores. If sufficient chlorinated solvent is present in the soil, the soil pores become saturated. Additional chlorinated solvent continues to migrate in the soil until it encounters a physical barrier or a water table. If the chlorinated solvent encounters a water table, the chlorinated solvent disperses until it encounters, accumulates, and overcomes the water table's capillary forces. At this point, the chlorinated solvent, which has a greater density than water, penetrates the water table's surface. The chlorinated solvent migrates under the force of gravity until its amount has been diminished through sorption, or until the chlorinated solvent encounters an aquitard.
In recent years, soil and groundwater contamination by chlorinated solvents has become an environmental problem. Chlorinated ethylenes, such as trichloroethylene (TCE), tetrachloroethylene (commonly known as perchloroethylene (PCE)), and chlorinated ethanes, such as 1,1,1-trichloroethane (TCA), which have been used as degreasing agents in a variety of industrial applications, pose environmental problems. Even though chlorinated degreasing agent use was curtailed in 1976, improper storage and uncontrolled disposal practices have resulted in contamination. Due to the high water solubility of chlorinated solvents, for example about 1100 mg/L TCE at 25° C., chlorinated solvents are highly mobile in soils and aquifers, and should be removed before dispersing too far. Therefore, a treatment to remove chlorinated solvents from contaminated soil and groundwater is needed.
A pump-and-treat method is a proposed treatment method removing contaminants from contaminated groundwater. The treatment usually involves withdrawing contaminated water from a well, volatilizing the contaminants in an air stripping tower, and adsorbing vapor-phase contaminants into granular-activated-carbon (GAC). There are limitations to this pump-and-treat method. The method is relatively inefficient, and some sites can require treatment for extended periods of time.
Chlorinated solvents can be degraded into less harmful materials by a method commonly referred to as “reductive dechlorination,” in which chlorine is replaced by hydrogen. The reductive dechlorination uses metallic, solid reaction elements, such as iron and zinc, to degrade chlorinated solvents and other organic compounds. For example, Gillham, U.S. Pat. No. 5,266,213, discloses feeding contaminated groundwater through a trench containing iron to degrade contaminants. The Gillham process is conducted under strict exclusion of oxygen and occurs over a long time period. The Gillham process often requires large amounts of iron for complete reaction. Furthermore, it is difficult to introduce large volumes of solid reaction material, such as iron, using the Gillham process at effective depths for in situ remediation.
Another process proposed for removing contaminants from contaminated media is soil vapor extraction. In this process, contaminated media, such as contaminated soil is removed from the its location and treated to remove contaminants and vapor. The soil vapor extraction process is labor extensive and often is inefficient as recalcitrant fractions of the contaminants remain in the soil. Further, the soil vapor extraction process, as well as the above-described pump-and-treat process, is very difficult to use in some soils. For example, neither of the soil vapor extraction process nor the pump-and-treat process, are particularly useful to treat contaminants in tight, clayey soils.
Therefore, a process that effectively treats contaminated media, such as contaminated soils and groundwaters, is needed. Further, a process that enables control of potential difference in response to contaminant content monitoring is needed.
SUMMARY OF THE INVENTION
The invention sets forth a method for treating a contaminated media. The method comprises disposing electrodes at the contaminated media, injecting a salt-containing solution into contaminated media, applying an electric voltage between electrodes imposed peripherally to the region, forming ions from the salt-containing solution, and migrating the ions between the electrodes across the contaminated media. The ions of the salt-containing solution migrate into at least a portion of the contaminated media to treat the contaminated media.
In another aspect, the invention sets forth a method for treating a contaminated media. The method comprises steps of determining a location of an iron(III)-bearing composition zone; disposing electrodes proximate the contaminated media, injecting a solution containing a sulfide salt proximate the zone, controlling an electric voltage between the electrodes and across the zone to migrate an ion of the sulfide salt to at least a portion of the contaminated media, wherein the sulfide salt reacts to produce a ferrous sulfide barrier zone, and controlling an electric voltage between electrodes to create a voltage gradient to cause electroosmotic movement of the contaminants through the contaminated media and to the barrier zone.
A further method of the invention comprises treating a contaminated media. This method includes disposing electrodes proximate the contaminated media, determining a region of low permeability in the contaminated media comprising contaminants, injecting a solution containing a remediating salt proximate the contaminated media, and controlling an electric voltage applied across the electrodes to cause an ion of the remediating salt to migrate to the contaminated media.
REFERENCES:
patent: 5074986 (1991-12-01), Probstein et al.
patent: 5120414 (1992-06-01), Carson et al.
patent: 5362394 (1994-11-01),
Shapiro Andrew Philip
Sivavec Timothy Mark
Thornton Roy Fred
General Electric Company
Gorgos Kathryn
Johnson Noreen C.
Parsons Thomas H
Stoner Douglas E.
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