Transvinylation process for the preparation of thermally labile

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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560 1, 560 71, 560104, 560113, 560189, 560 95, 560201, 560261, 568685, 568687, C07C 67343

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051552531

ABSTRACT:
A process for the transvinylation of a vinyl derivative of a Bronsted acid with a different Bronsted acid which comprises providing a liquid phase mixture containing said vinyl derivative and said Bronsted acid in the presence of a ruthenium compound at a temperature at which transvinylation occurs and recovering as a product of transvinylation the vinyl derivative of the different Bronsted acid. The process is most favorably employed using carboxylic acids to make vinyl esters of carboxylic acids.

REFERENCES:
patent: e27663 (1973-06-01), Fernholtz et al.
patent: 2245131 (1942-09-01), Herrmann et al.
patent: 2299862 (1942-10-01), Toussaint et al.
patent: 2989554 (1961-06-01), Mayne et al.
patent: 2997494 (1961-08-01), Brown
patent: 3000918 (1961-09-01), Wilip et al.
patent: 3117145 (1964-01-01), Ehrreich
patent: 3158633 (1964-11-01), Port et al.
patent: 3179641 (1965-04-01), Brown et al.
patent: 3188319 (1965-06-01), Smidt et al.
patent: 3201357 (1965-08-01), Fang et al.
patent: 3337611 (1967-08-01), Beardon, Jr.
patent: 3391130 (1968-07-01), Bolstad et al.
patent: 3454644 (1969-07-01), Dewhirst
patent: 3560534 (1971-02-01), MacDonald
patent: 3579562 (1971-05-01), Weigert
patent: 3647832 (1972-03-01), Chabardes et al.
patent: 3725305 (1973-04-01), Wilkinson
patent: 3751449 (1973-08-01), Gobran et al.
patent: 3755387 (1973-08-01), Young
patent: 3786102 (1974-01-01), Godfrey
patent: 3793355 (1974-02-01), Wilkinson
patent: 3965155 (1976-06-01), Smith et al.
patent: 3965156 (1976-06-01), Smith et al.
patent: 4112235 (1978-09-01), Schmerling
patent: 4175056 (1979-11-01), Antos
patent: 4415499 (1983-11-01), Blum et al.
patent: 4424359 (1984-01-01), Kaschig et al.
patent: 4446073 (1984-05-01), Qualeatti et al.
patent: 4458088 (1984-07-01), Hardman et al.
patent: 4640302 (1987-02-01), Drent
patent: 4647691 (1987-03-01), Lin et al.
patent: 4658053 (1987-04-01), Green
patent: 4664851 (1987-05-01), Drent
patent: 4731467 (1988-03-01), Drent et al.
patent: 4981973 (1991-01-01), Murray
Sandler, S. R., Journal of Chemical and Engineering Data, vol. 14, No. 4, Oct. 1966, pp. 503-506.
Slinckx, G. and Smets, G., Tetrahedron, vol. 22, 1966, pp. 3163-3171.
Hopff, H. and Osman, Maged A., Tetrahedron, vol. 24, 1968, pp. 3887-3890.
Adelman, R. L., Journal Organic Chemistry, 14, 1949, pp. 1057-1077.
Henry, P. M., Accounts of Chemical Research, vol. 6, 1973, pp. 16-24.
Sabel, A. et al., Chem. Ber. 102, 1969, pp. 2939-2950.
McKeon, J. E., et al. Tetrahedron, vol. 28, 1972, pp. 227-238.
Secemski, I. I. et al., Journal of the American Chemical Society, vol. 93, No. 14, 1971, pp. 3547-3550.
Henry, P. M., Journal of the American Chemical Society, vol. 93, No. 16 1971, pp. 3853-3859.
Henry, P. M., Journal of the American Chemical Society, vol. 94, No. 21, 1972, pp. 7311-7322.
Pandey, R. N. et al., Canadian Journal of Chemistry, vol. 53, 1975, pp. 2223-2231.
Allen, N. P. et al., Inorganica Chimica Acta, 28, 1978, pp. 231-235.
Rotem, M. et al., Organometallics, 2, 1983, pp. 1689-1691.
Mitsudo, T. et al., J. Org. Chem., vol. 50, No. 9, 1985, pp. 1566-1568.
Mitsudo, T. et al., J. Org. Chem., vol. 52, No. 11, 1987, pp. 2230-2239.
Vinyl Polymers (Acetate), Kirk-Othmer Encyclopedia of Chemical Technology, Third Edition, vol. 23, pp. 817-847.
Crooks, G. R. et al., J. Chem. Soc. (A), 1969, pp. 2761-2766.
Cotton, F. A. et al., Chemical Communications, 1971, pp. 967-968.
Spencer, A. et al., J. C. S. Dalton, 1972, pp. 1570-1577.
Legzdins, P. et al., J. Chem. Soc. (A), 1970, pp. 3322-3326.
Gareev, G. A. et al., Zhurnal Organicheskoi Khimii, vol. 13, No. 3, 1977, pp. 606-607.
Robinson, S. D. et al., J. C. S. Dalton, 1973, pp. 1912-1920.
Fouda, S. A. et al., Inorganic Chemistry, vol. 17, No. 11, 1978, pp. 3213-3220.
Spencer, A., Inorg. Nucl. Chem. Letters, vol. 12, 1976, pp. 661-663.
Komiya, S. et al., Chemistry Letters, 1987, pp. 1287-1290.

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