Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters
Patent
1997-01-13
1998-04-21
Barts, Samuel
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acid esters
560118, 560119, 560120, C07C 6974
Patent
active
057419256
ABSTRACT:
Vinyl naphthenate monomer mixtures are prepared by transvinylation of naphthenic acid in the presence of a catalyst of a palladium carboxylate complexed with one or more aryl N-containing ligands and distilling the resulting vinyl naphthenate monomers in the presence of the catalyst at pot temperatures exceeding 80.degree. C. The catalyst is stable and can be re-used over several transvinylation reaction runs.
REFERENCES:
patent: 4981973 (1991-01-01), Murray
patent: 5214172 (1993-05-01), Waller
patent: 5223621 (1993-06-01), Vallejos et al.
Ketterling, et al. Applied Catalysis, vol. 66 (1990), pp. 123-132.
Kem Kenneth Merle
Mao Chung-Ling
Waller Francis Joseph
Air Products and Chemicals Inc.
Barts Samuel
Bongiorno Mary E.
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