Transport of ethyne in form of α-alkynols as ethyne...

Chemistry of hydrocarbon compounds – Miscellaneous process – e.g. – indeterminate modification of a...

Reexamination Certificate

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Reexamination Certificate

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08003843

ABSTRACT:
The present invention relates to a new method for a safe transport of ethyne in form of α-alkynols as precursors for ethyne. The new method comprises three steps. In a first step the synthesis of the α-alkynol(s) is performed by reacting ethyne with (a) carbonyl compound(s). The second step comprises the transport of the resulting α-alkynol(s) in a safe manner, whereas the safety requirements for this transport are not as high as for ethyne because α-alkynol(s) are normally classified for transportation as hazardous class 3. In the third step the α-alkynol(s) can be cleaved and the ethyne and the carbonyl compound(s) can be obtained in the cleavage reaction and can be separated to yield pure products for further applications.

REFERENCES:
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International Search Report for PCT/EP2007/002885, mailed Jul. 30, 2007.
Written Opinion of the International Searching Authority for PCT/EP2007/002885, mailed Jul. 30, 2007.
Thompson, A.F. et al., “The Preparation and Properties of Certain Acetylenic Tertiary Carbinols”, J. Am. Chem. Soc., vol. 63, No. 1, pp. 186-188, (1941).
Huang, M. et al., “Reactions of Methylbutynol on Alkali-Exchanged Zeolites. A Lewis Acid-Base Selectivity Study”, Catalysis Letters, vol. 18, pp. 373-389, (1993).

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