Transparent glass-ceramics containing mullite

Glass manufacturing – Processes – Devitrifying glass or vitrifying crystalline glass

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501 5, C03C 322

Patent

active

045198284

ABSTRACT:
This invention is concerned with the production of substantially transparent glass-ceramic articles containing mullite as the predominant crystal phase which can be prepared by crystallizing in situ precursor glasses capable of being melted at temperatures no higher than 1650.degree. C. The inventive articles consist essentially, in weight percent, of 10-70% SiO.sub.2, 7-40% B.sub.2 O.sub.3, 14-50% Al.sub.2 O.sub.3, 0-35% RO, wherein RO consists of at least one member of the group in the indicated proportions of 0-15% MgO, 0-20% CaO, 0-30% SrO, 0-30% BaO, and 0-30% PbO, and 0-30% R.sub.2 O, wherein R.sub.2 O consists of at least one member of the group in the indicated proportions of 0-10% Li.sub.2 O, 0-15% Na.sub.2 O, 0-25% K.sub.2 O, 0-25% Rb.sub.2 O, and 0-25% Cs.sub.2 O, the mole ratio Al.sub.2 O.sub.3 :RO+R.sub.2 O>1.3. Where 0.01-1% Cr.sub.2 O.sub.3 is included in the composition, the glass-ceramic will exhibit broad absorption over the visible region of the radiation spectrum, strong fluorescence in the red and near infrared portions of the spectrum where exposed to ultraviolet and/or visible radiation, and relatively little overlap of the absorption and fluorescent spectra.

REFERENCES:
patent: 3146114 (1964-08-01), Kivlighn
patent: 3540895 (1970-11-01), Scheidler et al.
patent: 3681102 (1972-08-01), Beall
patent: 3881945 (1975-05-01), Trojer et al.
patent: 3905824 (1975-09-01), Grossman
patent: 4285728 (1981-08-01), Babcock et al.

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