Transition metal substituted polyoxometalates and process...

Details Transition metal substituted polyoxometalates and process... Transition metal substituted polyoxometalates and process...

2007-01-19

2010-10-26

Sullivan, Daniel M (Department: 1621)

Chemistry of hydrocarbon compounds

Aromatic compound synthesis

C585S500000, C585S706000, C423S263000, C423S463000, C423S464000

Reexamination Certificate

active

07820868

ABSTRACT:
This invention relates to polyoxometalates represented by the formula (An)m+[My(H2O)pXzZ2W18O66]m−1or solvates thereof, wherein A represents a cation acting as counterion of the polyanion, n is the number of the cations A, m is the charge of the polyoxoanion, M represents a transition metal selected from Cu, Zn, Pd, Pt and mixtures thereof, y is the number of transition metals M and is a number from greater than 4 to less than 6, p is a number of water molecules and is a number from 0 to 10, X is a halide selected from F, Cl, Br, I and mixtures thereof, z is a number of halides and is a number from 0 to 6 and Z represents a heteroatom selected from SbIII, BiIII, AsIII, SeIVand TeIV.

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