Transition metal oxide based calorimetric non-methane hydrocarbo

Chemical apparatus and process disinfecting – deodorizing – preser – Analyzer – structured indicator – or manipulative laboratory... – Means for analyzing gas sample

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422 83, 422 94, 422 95, 422 97, 422 98, 436133, 436134, 436137, 436141, 436143, 436147, 436149, 436152, 65 605, 65 6052, 4271263, 4271266, G01N 2716

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057361045

ABSTRACT:
A transition metal oxide based calorimetric non-methane hydrocarbon sensor (100) is constructed by disposing a transition metal based catalyst (105), preferably chromium oxide (Cr.sub.2 O.sub.3), onto a carrier (101). A temperature measurement device (103) is positioned thermally coupled to the transition metal based catalyst (105). A preferred application includes sensing non-methane heavy hydrocarbons in an automotive exhaust gas stream (803) by exposing a transition metal oxide catalyst based sensor (805) to the exhaust gas stream (803) and providing a signal (811) indicative of a concentration of non-methane heavy hydrocarbons and carbon monoxide (CO). Then, exposing a compensating sensor (807) to the same exhaust gas stream (803) and providing a compensating signal (813) indicative of a concentration of carbon monoxide (CO). By combining the signal (811) and the compensating signal (813), a measure of non-methane heavy hydrocarbons can be provided.

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Allan Symons, Catalytic Gas Sensors, 1992, pp. 169-185.

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