Transition metal catalytic systems and methods for preparing...

Details Transition metal catalytic systems and methods for preparing... Transition metal catalytic systems and methods for preparing...

2011-04-19

2011-04-19

Lu, Caixia (Department: 1765)

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Polymers from only ethylenic monomers or processes of...

C526S165000, C526S348000, C526S352000, C526S943000, C502S103000, C502S152000, C556S053000

Reexamination Certificate

active

07928173

ABSTRACT:
Provided are transition metal catalytic systems for preparing ethylene homopolymers or copolymers of ethylene with α-olefins. More specifically, provided are Group 4 transition metal catalysts, which is characterized in that the catalyst comprises around the Group 4 transition metal a cyclopentadiene derivative, and at least one aryloxide ligand(s) having a fluorenyl group or a derivative thereof (which is ready to be substituted at 9-position) that functions as an electron donor and serves to stabilize the catalytic system by surrounding an oxygen atom that links the ligand to the transition metal at ortho-position, and there is no cross-linkage between the ligands; catalytic systems comprising such transition metal catalyst and aluminoxane cocatalyst or boron compound cocatalyst; and processes for preparing ethylene homopolymers or copolymers of ethylene with α-olefins by using the same.

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