Trans-N-acyl-N-alkyl-1-amino-1,3-butadienes, trans-N-acyl-N-aryl

Details Trans-N-acyl-N-alkyl-1-amino-1,3-butadienes, trans-N-acyl-N-aryl Trans-N-acyl-N-alkyl-1-amino-1,3-butadienes, trans-N-acyl-N-aryl

1977-09-21

1978-08-08

Thomas, Jr., James O.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

C07C10118

Patent

active

041058534

ABSTRACT:
Trans-N-acyl-N-alkyl-1-amino-1,3-butadienes are prepared by contacting a conjugated azomethine with a strong base in an inert organic solvent at sub-zero temperature and thereafter acylating the resulting product. The trans-N-acyl-N-alkyl-1-amino-1,3-butadienes are useful as intermediates in the formation of substituted decahydro-quinolines, Pumiliotoxin C, and can also be used as the diene in Diels-Alder reactions or can be copolymerized with vinyl compounds.

REFERENCES:
patent: 3048619 (1962-08-01), Pray

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