Trans-beta-isocyanatoacrylate esters, their preparation, and pol

Organic compounds -- part of the class 532-570 series – Organic compounds – Isocyanate esters

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560356, 560205, C07C26506, C07C26508

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active

053470443

ABSTRACT:
Novel trans-beta-isocyanatoacrylate esters, their preparation and use in forming novel polymeric compositions, including polymers useful as adhesives, are disclosed. The trans-beta-isocyanatoacrylate esters have the formula: ##STR1## wherein R is C.sub.1 -C.sub.18 linear or branched alkyls; C.sub.5 -C.sub.6 cycloalkyl; aryl; alkaryl; aralkyl; C.sub.1 -C.sub.18 halogenated alkyl; halogenated aryl; C.sub.1 -C.sub.8 alkoxyalkyl; or alkoxyaryl.

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Kircheldorf, Angrew. Chem. Internat. Edit., 1972, vol. 11, pp. 128-129.
Kircheldorf, Makromonolokulare Chemic, 1973, vol. 173, pp. 13-41.
Washburne et al., Journal of Organic Chemistry, 1972, vol. 37, pp. 1738-1742.
"Organic Reaction", 1946, vol. 3, p. 342.
Byerley, et al., "Isocyanatoacrylates: A New Multifunctional Adhesive: Monomer Synthesis and Polymerization", Mar. 8, 1990, p. 3.
Byerley, et al., Journal of Dental Research Abstracts, "Isocyanatoacrylates; A New Multifunctional Adhesive: Monomer Synthesis and Polymerization", 1990, p. 116, Abstract No. 59.

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