Trans-3-substituted-1-indanol and insecticidal ester derivatives

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 3334

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active

045284083

ABSTRACT:
Disclosed are novel compounds of the formula ##STR1## in which R.sup.1 is hydrogen or methyl; R.sup.2 is phenyl or phenylmethyl either of which is optionally ring substituted with lower alkyl or halogen; R is hydrogen, a tetramethylcyclopropanecarbonyl group, a 1-(substitutedphenyl)-2-methylpropylcarbonyl group, a 1-(4-ethoxyphenyl)-2,2-dichlorocyclopropanecarbonyl group, or a substitutedvinylcyclopropanecarbonyl group; and, with respect to the indanyl substituents, the 1,3-trans isomer is present in an isomeric excess over the corresponding 1,3-cis isomer. The compounds wherein R is other than hydrogen are insecticides, and the compounds wherein R is hydrogen are insecticide intermediates.

REFERENCES:
Schering, "Chemical Abstracts", vol. 52, pp. 20107-20108, and 11943c, (1957).
Tsybib et al., "Chemical Abstracts", vol. 71, (1969), p. 38146f.
Barltrop et al., "Chemical Abstracts", vol. 52, p. 2690, (1957).

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