Total synthesis of the utero-evacuant substance d,l-zoapatanol

Details Total synthesis of the utero-evacuant substance d,l-zoapatanol Total synthesis of the utero-evacuant substance d,l-zoapatanol

1978-12-18

1980-12-16

Milestone, Norma S.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

26034854, 2603409R, 2603459R, C07D31304

Patent

active

042396891

ABSTRACT:
A method for the synthesis of racemic 2S*, 3R*-6E-(2"-hydroxyethylidene)-2-methyl-2-(4',8'-dimethyl-5'-oxo-7'-nonenyl )-oxepan-3-ol is described. The naturally occurring product, 2S, 3R-6E-(2"-hydroxyethylidene)-2-methyl-2-(4',8'-dimethyl-5'-oxo-7'-nonenyl) -oxepan-3-ol, is one of the active components of the zoapatle plant.

REFERENCES:
patent: 4060604 (1977-11-01), Kanojia
patent: 4086358 (1978-04-01), Wachter et al.
patent: 4112078 (1978-09-01), Chen

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