Total synthesis of benzene from non-hydrocarbon materials

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260679R, 423439, C07C 302, C07C 1124

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active

040092194

ABSTRACT:
A method of producing benzene on a high yield basis is disclosed in which non-hdyrocarbon carbonaceous raw materials are reacted with an alkali metal or an alkaline earth metal in the form of molten metal, metallic hydroxide or metallic oxide to produce the metallic carbide; the metallic carbide is hydrolyzed to produce acetylene; and the acetylene is cyclized to benzene. Side reactions are controlled to maximize yields. Benzene may be used to extend gasoline.

REFERENCES:
patent: 2642347 (1953-06-01), Gilbert
patent: 2802723 (1957-08-01), Lemke
patent: 2846940 (1958-08-01), Witt
patent: 3365510 (1968-01-01), Noakes
patent: 3655804 (1972-04-01), Pennella
patent: 3714323 (1973-01-01), Dolci et al.
M. A. Tamers "Synthesis of Liquid Scintillation Solvents" Molecuar Crystals 4 261-276 (1968).
Acta Cientifica Venezolana 16, No. 5, 156-162 (1965).

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