Tosylation of alcohols

Details Tosylation of alcohols Tosylation of alcohols

1992-01-29

1993-03-16

Siegel, Alan

Organic compounds -- part of the class 532-570 series

Organic compounds

Sulfonate esters

558 51, 558 52, 558 53, 558 56, 558 57, C07C30300, C07C30700, C07C31100

Patent

active

051946513

ABSTRACT:
A process is disclosed for the preparation of aliphatic toluenesulfonates. The process comprises reacting a solution of an aliphatic alcohol and an alkali metal hydroxide in a solution of an aprotic solvent with toluenesulfonyl chloride for from about 1 to about 12 hours and forming said aliphatic toluenesulfonate. These compounds are useful intermediates in the preparation of complex organic molecules.

REFERENCES:
Hoffman J. Chem. Soc. (London) (1965) 6748-6753.
Foldi Berichte, 60B, 656 (1927).

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