Torch for inductively coupled plasma spectrometry

Optics: measuring and testing – By dispersed light spectroscopy – With sample excitation

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G01N 2173

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056845812

ABSTRACT:
A torch for Inductively Coupled Plasma Spectrometry (ICPS) is formed from quartz and has inner and outer tubes defining an annular channel. The end of the inner tube is within an end portion of the outer tube, to define a chamber for a plasma ball. An inlet for a main gas flow opens tangentially into the annular channel. The annular channel is configured so as to maximize the swirl component of this flow. To this end, a connection to the inlet is provided with an annular toroidal shape, having a cross-section to or larger than the inlet. Further, the inlet is mounted relatively close to the end of the inner tube, so as to minimise decay of the swirl component as the gas flows along the annular channel, the length of the annular channel being sufficient to ensure that the flow leaving the annular channel is uniform and has a uniform swirl component. This arrangement enables a significantly reduced consumption of gas to generate a plasma ball, and can give improved performance, in terms of a higher detection rate in a spectrometer.

REFERENCES:
patent: 3467471 (1969-09-01), Greenfield et al.
patent: 4035604 (1977-07-01), Meleka et al.
patent: 4551609 (1985-11-01), Falk
C.D. Allemand and R.M. Barnes, A Study of Inductively Coupled Plasma Torch Configurations, Applied Spectroscopy, vol. 31, No. 5, 1977, pp. 434-443.
J.L. Genna, R.M. Barnes and C.D. Allemand, Modified Inductively Coupled Plasma Arrangement for Easy Ignition and Low Gas Consumption, Analytical Chemistry, vol. 49, No. 9, Aug. 1977, pp. 1450-1453.
R. Rezaaiyaan, G.M. Hieftje, H. Anderson, H. Kaiser and B. Meddings, Design and Construction of a Low-Flow, Low-Power Torch for Inductively Coupled Plasma Spectrometry, Applied Spectroscopy, vol. 36, No. 6, 1982, 627-631.
G. Angleys and J.M. Mermet, Theoretical Aspects and Design of a Low-Power, Low-Flow-Rate Torch in Inductively Coupled Plasma Atomic Emissions Spectroscopy, Applied Spectroscopy, vol. 38, No. 5, pp. 647-653.
A. Montaser, G.R. Huse, R.A. Wax, S.K. Chan, D.W. Golighty, J.S. Kane and A.F. Dorrzapf, Analytical Performance of a Low-Gas-Flow Torch Optimized for Inductively Coupled Plasma Atomic Emission Spectrometry, Analytical Chemistry, vol. 56, No. 2, Feb. 1984, pp. 283-288.
R. Rezaaiyaan and G. M. Hieftje, Analytical Characteristics of a Low-Flow, Low-Power Inductively Coupled Plasma, Analytical Chemistry, vol. 57, No. 2, Feb. 1985, pp. 412-415.
R.C. Ng, H. Kaiser and B. Meddings, Low Power Torches for Organic Solvents in Inductively Coupled Plasma Emission Spectrometry, Spectrochimica Acta., vol. 40B, Nos. 1/2, pp. 63-72, 1985.
L.L. Burton and M.W. Blades, A Comparison of Excitation Conditions Between Conventional and Low-Flow, Low-Power Inductively Coupled Plasma Torches, Applied Spectroscopy, vol. 40, No. 2, 1986, pp. 265-270.
Leo De Galan, M.T.C. De Loos-Vollebregt, Low-Gas-Flow Torches for ICP Spectrometry, Inductively Coupled Plasmas, Analytical Atomic Spectrometry, 2nd Ed., Chapter 18, 1992.
"A Low-Power Oxygen Inductively Coupled Plasma for Spectrochemical Analysis-I. Computer Simulation" by Pengyuan Yang in Spectrochimica Acta vol. 44B, No. 11, pp. 1081-1091, 1989.
"Inductively Coupled Argon Plasma Atomic Emission Spectrometry With an Externally Cooled Torch" by Peter A. M. Ripson et al. in Analytical Chemistry vol. 56, No. 13, pp. 2329-2335, Nov. 1984.
"A Low Argon Flow Inductively Coupled Plasma Torch Utilizing a Flame-Atomic Absorption Spectrometry Nebulizer" by M. D. Lowe in Applied Spectroscopy vol. 35, No. 1, pp. 126-128, Jan.-Feb. 1981.

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