Titanium hermetic seals

Glass manufacturing – Processes – Fusion bonding of glass to a formed part

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65 595, 65 321, 65 322, C03C 2702

Patent

active

H00014559

ABSTRACT:
Titanium is prenitrided by being heated in a nitrogen environment under conditions which give rise to the formation of a titanium-nitride surface layer on the titanium. Titanium thus prenitrided may be used in electrical components which are hermetically sealed using silicate glasses and standard glass sealing techniques. According to the method of the invention, alkali volatilization and formation of deleterious interfacial silicide are inhibited.

REFERENCES:
patent: 5104738 (1992-04-01), Brow et al.
patent: 5294241 (1994-03-01), Taylor et al.
"Kimble Glass Technical Data Sheet" (undated).
H. Rawson, et al., "The Glass Sealing Properties of Titanium and Zirconium", British Journal Applied Physics, vol. 5, Oct. 1954, pp. 352-353.
W. H. Kohl, Handbook of Materials and Techniques for Vacuum Devices, Reinhold Publishing Corp., N.Y., N.Y., 1967, pp. 401, and 415-416.
A. Passerone, et al., "The Titanium-Molten Glass System: Interactions and Wetting", Journal of Material Science 12, 1977, pp. 2465-2474.
Z. Feipeng, et al., "Wetting and Reactions in Glass/Titanium Systems", Proc. 33rd Pacific Coast ACS Meeting, 1980, pp. 76-78.
R. K. Brow, et al., "Reactions and Bonding Between Glasses and Titanium", Proc. Winter Meeting ASME MD-4, 1987, pp. 25-30.

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