Titanium diboride ceramic fiber composites for Hall-Heroult cell

Chemistry: electrical and wave energy – Apparatus – Electrolytic

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204243R, 204290R, 204291, 204294, 427113, 427122, 4271261, 4271262, 427255, 428113, 4283077, 501 95, C25C 702

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049293281

ABSTRACT:
An improved cathode structure for Hall-Heroult cells for the electrolytic production of aluminum metal. This cathode structure is a preform fiber base material that is infiltrated with electrically conductive titanium diboride using chemical vapor infiltration techniques. The structure exhibits good fracture toughness, and is sufficiently resistant to attack by molten aluminum. Typically, the base can be made from a mat of high purity silicon carbide fibers. Other ceramic or carbon fibers that do not degrade at temperatures below about 1000 deg. C can be used.

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Development of Monolithic Titanium Diboride Cathodes for Retrofit Hall Cell Applications, R. C. Dorward & J. R. Payne, U.S. DOE Report No. DOE/CS/40215/1.
An Evaluation of a Titanium Diboride-Composite Material as Cathodes for Low Energy Alumina Reduction Cells, R. C. Dorward Cathodes for Low Energy Alumina Reduction Cells, R. C. Doward & J. R. Payne, U.S. DOE Report No. DOE/CS/40215/2.
K. Billehaug et al., "Inert Cathodes for Aluminum Electrolysis in Hall-Heroult Cells (I)," Aluminum, V.56, pp. 643-648 (Jan. 1980).
W. A. Zdaniewski, "Role of Microstructure & Intergranular Phases in Stress Corrosion of TiB.sub.2 Exposed to Liquid Aluminum" J. Am. Ceram. Soc., vol. 68, pp. C-309-C-312 (1985).
C. B. Finch et al., "Crack Formation & Swelling of TiB.sub.2 -Ni Ceramics in Liquid Aluminum," J. Am. Society, vol. 65, #7, pp. C-100-C-101 (1982).
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