Titanium compound for photochemical reactions and method for pro

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

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423592, 423598, 423600, 423608, 423610, 423613, 502308, 502309, 502323, B01J 2300, C01B 1314, C01G 2300, C01F 702

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060228245

ABSTRACT:
A titanium compound for photochemical reactions having a high catalytic activity per unit surface area and extremely good stability to heat treatment is made of a substitutional solid solution of titanium oxide in which aluminum atoms occupy titanium sites of the titanium oxide uniformly at a predetermined ratio. Aluminum atoms preferably occupy about 0.01 to 0.5% of the titanium sites. The titanium compound for photochemical reactions is obtained from a complex alkoxide of titanium and aluminum.

REFERENCES:
"Synthesis of Thermally Stable Nanocrystalline Anatase by High-Temperature Hydrolysis of Titanium Alkoxide with Water Dissolved in Organic Solvent from Gas Phase"; Journal of Materials Science Letters; 15 (1996); pp. 197-200; by H. Kominami, Y. Takada, H. Yamagiwa, Y. Kera, M. Inoue and T. Inui.
"Preparation and Properties of Titania Pillared Clay"; Materials Chemistry and Physics; 17, (1987); pp. 87-101; by Shoji Yamanaka, Tatsuo Nishihara and Makoto Hattori.
Japan Chemical Society, 71st Autumn Annual Meeting; (1996), Preprints, p. 84, 4P1, .beta.24.
15th "Symposium on Photocatalyst Chemistry", p. 29; Japan.
Electrochemical Society, 1996 Autumn Meeting, Synopses, p. 234, 1I12; Japan .

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