Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Reexamination Certificate
2005-10-06
2010-06-08
Saeed, Kamal A (Department: 1626)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
C524S923000, C556S030000, C556S033000, C558S423000
Reexamination Certificate
active
07732544
ABSTRACT:
The present invention relates to a titanium compound produced from a reaction mixture of a titanium tetraalkoxide compound with water and an optically active ligand represented by the following general formula (1), or a titanium oxoalkoxide compound and an optically active ligand represented by the following general formula (1),wherein, in the formula, R2, R3and R4independently represent a hydrogen atom, an alkyl group or the like, and A* represents a hydrocarbon-containing group with three or more carbon atoms having an asymmetric carbon atom or axial asymmetry. The invention further relates to a process for producing optically active cyanohydrins which is characterized by reacting a carbonyl compound with a cyanating agent in the presence of such a titanium compound.
REFERENCES:
patent: 5-112518 (1993-05-01), None
patent: 2000-191677 (2000-07-01), None
patent: 2002-255985 (2002-09-01), None
patent: WO 02/10095 (2002-02-01), None
patent: WO 02/10095 (2002-02-01), None
Gama et al. “Steric effects in the design of chiral Schiff base-titanium complexes: new catalysts for asymmetric trimethylsilylcyanation of aldehydes” Tetrahedron: Asymmetry, 2002, vol. 13, pp. 149-154.
Brozda, et al. Tetrandron: Asymmetry, vol. 16, pp. 953-958 (2005).
Gama, et al. Tetrahdron: Asymmetry, vol. 13, pp. 149-154 (2002).
Bensari, et al. Org. Lett., vol. 3(24), pp. 3863-3865 (2001).
Hayashi, et al. J. Chem. Soc., Chem. Commun., vol. 3, pp. 341-342 (1994).
Angeles Gama et al., “Steric effects in the design of chiral Schiff base-titanium complexes: new catalysts for asymmetric trimethylsilylcyanation of aldehydes”, Tetrahedron:Asymmetry, 2002, pp. 149-154, No. 13, ISSN:0957-4166, XP-002468255, Elsevier Science Ltd.
Lucía Z. Flores-Lopéz et al., “Structure/Enantioselectivity Study of the Asymmetric Addition of Trimethylsilylcyanide to Benzaldehyde Catalyzed by Ti(IV)-Schiff Base Complexes”, Organometallics, 2000, pp. 2153-2160, No. 19, ISSN:0276-7333, XP-002468256, American Chemical Society.
Xiang-Ge Zhou et al., “Titanium and ruthenium binaphthyl Schiff base complexes as catalysts for asymmetric trimethylsilylcyanation of aldehydes”, Journal of the Chemical Society, Dalton Transactions, Chemical Society, 1999, pp. 3303-3309, No. 18, ISSN:1472-7773, XP-002201075, The Royal Society of Chemistry.
V.W. Day et al., “Solution Structure Elucidation of Early-Transition-Metal Polyoxoalkoxides Using17O Nuclear Magnetic Resonance Spectroscopy”, Journal of the American Chemical Society, 1991, pp. 8190-8192, vol. 113, No. 21, ISSN:0002-7863, XP-002468257, American Chemical Society.
Yuri N. Belokon et al.; “The Asymmetric Addition of Trimethylsilyl Cyanide to Aldehydes Catalyzed by Chiral (Salen)Titanium Complexes”; J. Am. Chem. Soc.; 1999; pp. 3968-3973; vol. 121; American Chemical Society.
Masahiko Hayashi et al.; “Asymmetric Carbon-Carbon Bond Forming Reactions Catalyzed by Chiral Schiff Base-Titanium Alkoxide Complexes”; Tetrahedron; 1994; pp. 4385-4398; vol. 50, No. 14; BPC-AUP Aberdeen Ltd., Great Britain.
Yaozhong Jiang et al.; “Asymmetric Synthesis XXII:Asymmetric Catalytic Trimethylsilylcyanation of Benzaldehyde by Novel (Ti(IV)-Chiral Schiff Base Complexes”; Tetrahedron:Asymmetry; Feb. 1995; pp. 405-408; vol. 6, No. 2; Elsevier Science, Ltd., Great Britain.
Miyazoe Satoru
Nagata Takushi
Yoshinaga Kazuhiko
Barker Michael
Buchanan & Ingersoll & Rooney PC
Mitsui Chemicals Inc.
Saeed Kamal A
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