Tire having radiation cured air barrier coating

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Compositions to be polymerized by wave energy wherein said...

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522174, 528 66, C08G 1832

Patent

active

050361139

ABSTRACT:
A tire has on its inner surface on elastomeric air barrier coating, which is formed by photocuring a composition comprising: (a) an end capped prepolymer (MW 2500-10,000) formed by reacting a polyester diol (MW750-1500) with a diisocyanate, and reacting the resulting diisocyanate terminated prepolymer with an end group forming compound; (b) one or more monofunctional addition polymerizable monomers; and (c) a photoinitiator or mixture thereof. In preferred embodiments, the polyester diol is hydroxyl terminated ethylene adipate, the diisocyanate is TDI, and the end group forming compound is 2-hydroxyethyl methacrylate (HEMA). The monofunctional monomer may be or include N-vinyl-pyrrolidone (NVP). The air barrier coating has high elongation, low modulus, good heat aging resistance and good adhesion to the tire in addition to low oxygen permeability.

REFERENCES:
patent: 4254230 (1981-03-01), Howard
patent: 4333963 (1982-06-01), Emmons et al.
patent: 4360540 (1982-11-01), Chong
"Tuftane" Technical Information and Selector Guide, Brochure DS 10-5001B, Lord Corporation/Film Products Division, Pa.

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