Three stage processes for the separation of supercritical or...

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

Reexamination Certificate

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C568S864000, C568S913000

Reexamination Certificate

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07084313

ABSTRACT:
Processes for separating supercritical or near-critical mixtures containing hydrogen, a solvent gas, methanol and a fatty alcohol under an initial pressure of from 100 to 300 bar are described, wherein the processes comprise: (a) reducing the pressure of such a mixture in a first stage to a pressure of from 50 to 150 bar to form a first recycle gas and a first partially-separated intermediate mixture, wherein the reduced pressure in the first stage is at least below the initial pressure; (b) reducing the pressure of the first partially-separated intermediate mixture in a second stage to a pressure of from 10 to 50 bar to form a second recycle gas and a second partially-separated intermediate mixture; and (c) reducing the pressure of the second partially-separated intermediate mixture in a third stage to a pressure of from 1 to 10 bar to form a third recycle gas and a fatty alcohol product.

REFERENCES:
patent: 4568653 (1986-02-01), Schwirten et al.
patent: 4714791 (1987-12-01), Inada et al.
patent: 5734070 (1998-03-01), Tacke et al.
patent: 5962711 (1999-10-01), Harrod et al.
patent: 6156933 (2000-12-01), Poliakoff et al.
patent: 0 791 041 (2001-04-01), None
patent: 60 214757 (1985-10-01), None
patent: WO 95/22591 (1995-08-01), None
“Supercritical, Single-Phase Hydrogenation Speeds Up The Production Of Fatty Alcohols,” Chemical Engineering News, (Dec., 2001), p. 17.

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