Thioresistant catalyst for methane production

Details Thioresistant catalyst for methane production Thioresistant catalyst for methane production

1988-06-15

1989-05-23

Shine, W. J.

Catalyst, solid sorbent, or support therefor: product or process

Catalyst or precursor therefor

Metal, metal oxide or metal hydroxide

518714, 518715, B01J 2310, B01J 2384, B01J 2385, B01J 2388

Patent

active

048331120

ABSTRACT:
A method of methane production with a thioresistant catalyst wherein a mixture comprising in particular carbon monoxide, hydrogen and sulphur compounds is contacted with a thioresistant catalyst comprising a metal selected from the group comprising molybdenum, vanadium or tungsten and possible cobalt and/or nickel, this catalyst being deposited onto a cerium oxide support, the reaction being performed at a temperature lying between about 250.degree. C. and 650.degree. C. and at a pressure lying between about 5 bars and 140 bars. This method is useful to carry out the effective methane synthesis with a much improved selectivity in favor of methane.

REFERENCES:
patent: 4260553 (1981-04-01), Happel et al.
patent: 4540714 (1985-09-01), Pedersen et al.

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