Thin layer electrode and cell

Details Thin layer electrode and cell Thin layer electrode and cell

1980-02-26

1982-01-12

Kaplan, G. L.

Chemistry: electrical and wave energy

Processes and products

Vacuum arc discharge coating

G01N 2730

Patent

active

043104002

ABSTRACT:
A thin layer electrolytic cell is disclosed in which the solution being studied is retained around the working electrode and separated from the electrolyte by an annular piece of a current conducting membrane. The membrane is preferably an ion selective membrane, preferably Nafion, a copolymer of tetrafluoroethylene and a vinylsulfonyl fluoride.

REFERENCES:
patent: 3634213 (1972-01-01), Coates
patent: 3657095 (1972-04-01), Tosteson
patent: 3743591 (1973-07-01), Steinhardt
A. T. Hubbard, CRC Critical Reviews in Analytical Chem., pp. 201-241, March 1973.
Chemie Ingenieur Technik, "Perfluorierte Kationenaustauscher-Polymere", Walther Grot, 1975, p. 617.
"Perfluorierte . . . thermischer Stabilitat", Walter Grot, 1972, pp. 167-169.
Simple Electrode for Thin-Layer Electrochemistry", J. C. Schaeffer & D.G. Peters, 1970, pp. 430-432.
"Chronopotentiometry in Thin Layers of Solution", C. R. Christensen & F. C. Anson, 1963, pp. 205-209.
"Conducting Glass Electrode . . . of Neptunium", R. C. Propst, 1971, pp. 994-999.
"Use of Nafion . . . Electrolytic Cells", Walther Grot, 1978, pp. 299-301.
"A New Dip-Type . . . Non-Aqueous Systems", J. E. McClure & D. L. Maricle, 1966, (3 pp.) (no page numbers).
"An Electrochemical . . . Thin Layer Electrode", T. P. DeAngelis & W. R. Heineman, 1976, pp. 594-597.
"Thin-Layer Coulometry: . . . Oxide Stoichiometry", J. M. LeCuire & Y. Pillet, 1978, pp. 99-106.

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