Thin film battery and electrolyte therefor

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Include electrolyte chemically specified and method

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C204S192150

Reexamination Certificate

active

07410730

ABSTRACT:
A solid amorphous electrolyte composition for a thin-film battery. The electrolyte composition includes a lithium phosphorus oxynitride material containing an aluminum ion dopant wherein the atomic ratio of aluminum ion to phosphorus ion (Al/P) in the electrolyte ranges greater than zero up to about 0.5. The composition is represented by the formula:in-line-formulae description="In-line Formulae" end="lead"?LitPxAlyOuNvSw,in-line-formulae description="In-line Formulae" end="tail"?where 5x+3y=5, 2u+3v+2w=5+t, t ranges from about 2.9 to about 3.3, x ranges from about 0.94 to about 0.85, y ranges from about 0.094 to about 0.26, u ranges from about 3.2 to about 3.8, v ranges from about 0.13 to about 0.46, and w ranges from zero to about 0.2. Thin film batteries containing such electrolyte films have less tendency to fail prematurely.

REFERENCES:
patent: 5338625 (1994-08-01), Bates et al.
patent: 5512147 (1996-04-01), Bates et al.
patent: 5561004 (1996-10-01), Bates et al.
patent: 5569520 (1996-10-01), Bates
patent: 5597660 (1997-01-01), Bates et al.
patent: 6168884 (2001-01-01), Neudecker et al.
patent: 6242132 (2001-06-01), Neudecker et al.
patent: 6365300 (2002-04-01), Ota et al.
patent: 1052718 A11 (2000-11-01), None
patent: 2000340257 (2000-12-01), None
patent: 2001319520 (2001-11-01), None
V.K. Deshpande, A. Pradel, and M. Ribes, “The Mixed Glass Former Effect in the Li2S:SiS2:GeS2 System”, Mat. Res. Bull. vol. 23, No. 3, pp. 379-384 (1988).
R. Creus, J. Sarradin, R. Astier, A. Pradel, and M. Ribes, “The Use of Ionic And Mixed Conductive Glasses in Microbatteries”, Mater. Sci. and Eng. B3, pp. 109-112 (1989).
J.B. Bates, N.J. Dudney, G.R. Gruzalski, R.A. Zuhr, A. Choudhry, C.F. Luck, “Electrical Properties of Amorphous Lithium Electrolyte Thin Films,” Solid State Ionics 53-56, pp. 647-654 (1992).
J.B. Bates, G.R. Gruzalski, N.J. Dudney, and C.F. Luck, “New Amorphous Thin-Film Lithium Electrolyte and Rechargeable Microbattery,” p. 337 in Proceedings of 35thInternational Power Sources Symposium, Institute of Electrical and Electronics Engineers, Piscataway, New Jersey, 1993.
K. Takada, N. Aotani, and S. Kondo, “Electrochemical Behaviors of Li+ Ion Conductor, Li3P04-Li2S-SiS2”, J. Power Sources 43-44, pp. 135-141 (1993).
S.D. Jones and J.R. Akridge, “A Thin-Film Solid-State Microbattery”, J. Power Sources 43-44, pp. 505-513 (1993).
K. Iwamoto, N. Aotani, K. Takada, and S. Kondo, “Rechargeable Solid State Batter with Lithium Conductive Glass, Li3PO4-Li2S-SiS2”, Solid State Ionics 70/71, pp. 658-661 (1994).
J.B. Bates, G. R.Gruzalski, N.J. Dudney, C.F. Luck, and X. Yu, “Rechargeable Thin-Film Lithium Batteries,” Solid State Ionics 70/71, pp. 619-628 (1994).
X. Yu, J.B. Bates, G.E. Jellison, Jr., and F.X. Hart, “A Stable Thin-Film Lithium Electrolyte: Lithium Phosphorous Oxynitride,” J. Electrochem. Soc. vol. 144, No. 2, pp. 524-532 (1997).
J.B. Bates, N.J. Dudney, B.J. Neudecker, F.X. Hart, H.P. Jun, and S.A. Hackney, “Preferred Orientation of Polycrystalline LiCoO2 Films,” J. Electrochem. Soc., 147 (1), pp. 59-70 (2000).
J.B. Bates, N.J. Dudney, B. Neudecker, A. Ueda, and C.D. Evans, “Thin-Film Lithium and Lithium-Ion Batteries,” Solid State Ionics 135, pp. 33-45 (2000).
“Thin Film Battery Design”, Oak Ridge National Laboratory, web page, copyright 2001.
J.B. Bates, N.J. Dudney, G.R. Gruzalski, R.A. Zuhr, A. Choudhry, C.F. Luck, and J.D. Robertson, “Fabrication and characterization of Amorphous Lithium Electrolyte Thin Films and Rechargeable Thin Film Batteries” J. Power Sources pp. 43-44, 103 (1993).
M. Tomozawa, “Phase Separation in Glass”, in Treatise on Materials Science and Technology, vol. 17, p. 71, M. Tomozawa and R. H. Doremus, eds. (Academic Press, New York, 1979).

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Thin film battery and electrolyte therefor does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Thin film battery and electrolyte therefor, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Thin film battery and electrolyte therefor will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4009227

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.