Thiation process

Organic compounds -- part of the class 532-570 series – Organic compounds – Unsubstituted hydrocarbyl chain between the ring and the -c-...

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540488, 560 16, 560 10, 568 20, 558230, C07D26714

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active

046634525

ABSTRACT:
An organic carbonyl compound is thiated to the corresponding thiono compound by reacting it with phosphorus pentasulfide in the presence of an alkali metal bicarbonate and a hydrocarbon diluent. In preferred embodiments of the invention, the carbonyl compound is an amide, especially an aromatic amide, and the diluent is an inert hydrocarbon having a boiling point in the range of about 50.degree.-150.degree. C.

REFERENCES:
patent: 4439617 (1984-03-01), Sestanj et al.
Scheeren et al., "Synthesis" (1973) pp. 149-151.

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