Thermoplastic vulcanizates having improved adhesion to polar...

Stock material or miscellaneous articles – Composite – Of polyamide

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C428S476900, C525S066000

Reexamination Certificate

active

08071220

ABSTRACT:
Thermoplastic vulcanizate compositions having good adhesion to unheated polar substrates include an amount of functionalized polyolefin that comprises greater than 80% of the total polyolefin of the TPV. The functional group may be an anhydride. Exemplary TPVs may further include polyamide, and an elastomer, which may include one or more of conjugated diene rubber, unsaturated styrenic triblock copolymer rubber, hydrogenated styrenic triblock copolymer rubber, ethylene/alpha-olefin rubber, and ethylene/alpha-olefin
on-conjugated diene rubber. The TPVs may have hardness values of less than 85 Shore A and peel forces with respect to unheated polar substrates of greater than 15 pli. Articles comprising polar substrates and TPVs are also taught.

REFERENCES:
patent: 4957968 (1990-09-01), Adur et al.
patent: 5574105 (1996-11-01), Venkataswamy
patent: 5843577 (1998-12-01), Ouhadi et al.
patent: 5936039 (1999-08-01), Wang et al.
patent: 5955547 (1999-09-01), Roberts et al.
patent: 6028142 (2000-02-01), Garois
patent: 6062283 (2000-05-01), Watanabe et al.
patent: 6300418 (2001-10-01), Brzoskowski et al.
patent: 6475633 (2002-11-01), Robert et al.
patent: 6663975 (2003-12-01), Toyosawa et al.
patent: 2004/0014897 (2004-01-01), Pradel et al.
patent: 2004/0132907 (2004-07-01), Nakamura et al.
patent: 2004/0213933 (2004-10-01), Varma
patent: 2006/0084764 (2006-04-01), Hanna et al.
patent: 2006/0283314 (2006-12-01), Cesaroni
patent: 2007/0246246 (2007-10-01), Vilkman et al.
patent: 2009/0068386 (2009-03-01), Emad et al.
patent: 2009/0069487 (2009-03-01), Gu et al.
patent: 0 753 027 (1997-10-01), None
patent: 2 107 325 (1983-04-01), None
patent: WO 95/26380 (1995-10-01), None
patent: WO 00/36011 (2000-06-01), None
patent: WO 00/37553 (2000-06-01), None
patent: WO 00/49088 (2000-08-01), None
T. Hagiwara et al., “Rapid Communications: Functionalization and Applications of Telechelic Oligopropylenes. II. Introduction of Succinic Anhydride Units and Preparation of Multiblock Copolyolefins by Polycondensation”, Journal of Polymer Science Part A: Polymer Chemistry, 2006, vol. 44, pp. 3406-3409.
M. Xanthos et al., “Impact Modification of Aromatic/Aliphatic Polyamide Blends: Effects of Composition and Processing Conditions”, Journal of Applied Polymer Sciences, 1996, vol. 62, pp. 1167-1177.
T. Kang et al., “Effects of Amorphous Nylon on the Properties of Poly(Butylene Terephthalate)and 70/30 Poly(Butylene Terephthalate)/Nylon 6 Blends”, Polymer Engineering and Science, 1996, vol. 36, Issue 20, pp. 2525-2533.
G. Holden et al., “Styrenic Thermoplastic Elastomers”, Thermoplastic Elastomers 2ndEdition, Hauser/Gardner Publications, Inc., Cincinnati, OH, 1996, Ch. 3, pp. 48-68.
G. Moad, “The Synthesis of Polyolefin Graft Copolymers by Reactive Extrusion”, Progress in Polymer Science vol. 24, 1999, pp. 81-142.
J. Zimmerman, “Polyamides”, Encyclopedia of Polymer Sciences and Engineering, ed. J. Kroschwitz et al., 1988, vol. 11, pp. 315-381.
H. Torre, “Transparent Nylons”, Nylon Plastics Handbook, M. Kohan ed., 1995, pp. 377-387.
DuPont Elvamide Resins, Product and Properties Guide, Jun. 2002, pp. 1-20 (downloaded from www.plastics.dupont.com).
V. Smits et al., “SI-Based Technology for Thermoplastic Vulcanizates,”TPE 2005 International Conference, Rapra Technology Ltd, RAPRA Technology, Berlin, Germany, Paper 4, Sep. 14-15, 2005, pp. 1-12.
Ohlsson et al., “Improved compatibility between polyamide and polypropylene by the use of maleic anhydride grafted SEBS,” Polymer, XP004138360, Dec. 1998, vol. 39, No. 26, pp. 6705-6714.
Oshinski et al., “The role of matrix molecular weight in rubber toughened nylon 6 blends: 2 Room temperature Izod impact toughness,” Polymer, XP004069475, Oct. 1996, vol. 37, No. 22, pp. 4909-4918.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Thermoplastic vulcanizates having improved adhesion to polar... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Thermoplastic vulcanizates having improved adhesion to polar..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Thermoplastic vulcanizates having improved adhesion to polar... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4299866

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.