Thermoplastic resin laminate

Stock material or miscellaneous articles – Hollow or container type article – Polymer or resin containing

Reexamination Certificate

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Details

C428S420000, C428S421000, C525S199000, C525S200000

Reexamination Certificate

active

06440511

ABSTRACT:

FIELD OF THE INVENTION
The present invention relates to a thermoplastic resin laminate produced by firmly bonding two layers composed respectively of different types of thermoplastic resins which are not bonded each other.
RELATED ART
As a conventional laminating method of bonding two layers composed respectively of a thermoplastic resin A and a thermoplastic resin B, which are not. bonded each other, for example, a method of chemically modifying the surface and a method of physically modifying the surface by means of sputtering, corona discharge, plasma, excimer laser, etc. are known. These methods had a problem that an interlaminar bonding force is small although a special processing device is required. Furthermore, in order to obtain a resin laminate, a successive melt molding is required and therefore the number of steps at the time of molding increases, which results in poor processing productivity.
Even if a simultaneous co-extrusion method is used, it was limited to a co-extrusion method using a thermoplastic resin C which is bonded to both thermoplastic resin A and thermoplastic resin B.
SUMMARY OF THE INVENTION
The present invention provides a thermoplastic resin laminate comprising at least three thermoplastic resin layers, wherein an intermediate layer interposed between a first layer comprising a thermoplastic resin A
1
and a second layer comprising a thermoplastic resin B
1
, which are not bonded each other, comprises a thermoplastic resin composition which comprises as a main component a thermoplastic resin A
2
having a bonding property to the thermoplastic resin A
1
and a thermoplastic resin B
2
having a bonding property to the thermoplastic resin B
1
and forms a dispersion structure, wherein the thermoplastic resin A
2
forms a continuous phase and the thermoplastic resin B
2
forms a dispersed phase in the intermediate layer at the vicinity of the interface between the intermediate layer and the first layer, and wherein the thermoplastic resin B
2
forms the continuous phase and the thermoplastic resin A
2
forms the dispersed phase in the intermediate layer at the vicinity of the interface between the intermediate layer and the second layer.
According to the present invention, a firm bonding strength can be accomplished between the first layer of the thermoplastic resin A
1
and the second layer of the thermoplastic resin B
1
.


REFERENCES:
patent: 4886689 (1989-12-01), Kotliar et al.
patent: 5441782 (1995-08-01), Kawashima et al.
patent: 5716684 (1998-02-01), Stoeppelmann et al.
patent: 0523644 (1993-01-01), None
patent: 0642921 (1995-03-01), None
patent: 62 58615 (1987-12-01), None
patent: 63-275644 (1988-11-01), None
patent: 4 224939 (1992-08-01), None
patent: 5 60422 (1993-09-01), None
patent: 7 164602 (1995-06-01), None
patent: 7 173447 (1995-07-01), None
Japanese Publication No. 63-275644 A; published Nov. 14, 1988—Abstract Only.

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