Thermoelectric material

Compositions – Electrically conductive or emissive compositions – Metal compound containing

Reexamination Certificate

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C136S236100

Reexamination Certificate

active

07618562

ABSTRACT:
A p-type oxide thermoelectric material which has a high output factor and a low environmental load. The thermoelectric material is composed of an oxide represented by the compositional formula (Ni1-xCux) (Mn2-yCuy)O4and having a structure in which Ni elements occupying the Ni sites and/or Mn elements occupying the Mn sites are partially replaced by Cu elements, wherein 0≦x≦0.7, 0≦y≦0.7, and 0.4≦x+y. In such a thermoelectric material, preferably, 0.2≦x≦0.5 and 0.2≦y≦0.5, and preferably, the output factor at 50° C. to 800° C. is 10×10−6W/mK2or more.

REFERENCES:
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patent: 8-55706 (1996-02-01), None
patent: 2000-211971 (2000-08-01), None
Trollund et al “Cation distribution and electrochemical behavior of copper nickel manganese oxide (CuxNi0.6-0.2xMn2.4-0.8xO4)”, Electrochimica Acta (1990), 35(8), 1303-10. Abstract Only.
Toepfer et al “Investigations on the electronically conducting oxide systems XXIV: preparation and electrical proerties of the spinel series CuzNiMn2-zO4”, Solid State Ionics (1993), 59(3-4), 249-56.
Metz et al “Intergranular phases in electroceramics”, Journal de Physique, Colloque (1990), Cl, Interganular Interphase Boundaries Mater.), C1-1003/C1-1008. Abstract Only.
Gurav et al “Synthesis, characterization and catalyic CO oxidation studies over Ni1-xCuxMn2O4”, Indian Journal of Chemistry, Section A: (1999), 38A(2), 130-135. Abstract Only.
Kukuruznyak et al “Combinatorial screening of ternary NiO-Mn2O3-CuO composition spreads”, Journal of Applied Physica 98, 043710 1-4. (2005).
PCT/JP2007/058840 International Search Report dated May 29, 2007.
PCT/JP2007/058840 Written Opinion dated May 29, 2007.

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